Safety Data (MSDS)



Safety Data Sheet (MSDS)

Revision date: 11-12-2019
Version: 2.0.0

Synthetic resin paint

SECTION 1: Identification of the substance or mixture and of the company / undertaking

1.1. Product identification

Trade name: Synthetic resin paint

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use: Paint

1.3. Details of the supplier of the safety data sheet
 

Address: Breukelaarweg 33

Postal Code: 7051 DW

Location: VARSSEVELD

Country the Netherlands
 

Telephone: +31 (0) 315 254 370

1.4. Emergency telephone number

UK: Contact NHS advice service Tel: 111
UK: National Poisons Information Service  - Web Link: npcis.org

Holland: 030-274 8888 (National Poisons Information Centre)
 

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
 

CLP classification: Flam. Liq. 3; H226 Skin Sens. 1A; H317 STOT SE 3; H336
 

Most serious adverse effects:

Flammable liquid and vapour. May cause an allergic skin reaction. Can cause drowsiness or dizziness.
The product releases organic solvent vapours that can cause lethargy and dizziness.

 In high concentrations, the fumes cause headaches and intoxication.
Prolonged or repeated exposure of the skin or inhalation of vapours can damage to  the central nervous system.
Continuously absorbed into the skin, with symptoms such as dizziness and headache.


2.2. Label elements

Icons:


Signal words: Warning
Contains Substance: Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclic compounds, <2% aromatics;
Xylene; ethylbenzene; 2-butanone oxime; cobalt bis (2-ethylhexanoate)
H phrases
H226 Flammable liquid and vapor.
H317 May cause an allergic skin reaction.

H336 May cause drowsiness or dizziness.

 P phrases:

P101 When seeking medical advice, have the container or label available.

 P102 Keep out of reach of children. P103 Read label before use.

 P210 Keep away from heat, hot surfaces, sparks, open flames and others ignition sources. Do not smoke. 

P261 Avoid breathing dust / fume / gas / mist / vapor / spray. 

P280 Protective gloves / protective clothing / eye protection / face protection to wear. 

P303 + 361 + 353 IF ON SKIN (or hair): 

Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P304 + 340 IF INHALED: Remove person to fresh air and keep them safe can breathe easily. 

P501 Dispose of contents / container to a waste collection point in accordance with the local ordinances. 

*Additional information EUH066 Repeated exposure may cause skin dryness or cracking*

2.3. Other dangers No assessment has been performed to determine PBT and vPvB. 

SECTION 3: Composition / information on ingredients 

3.2. Mixtures






Please see section 16 for full text of H-phrases SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation: Get fresh air. Consult a doctor if the complaints persist.
Ingestion: Rinse mouth thoroughly and drink 1-2 glasses of water in small sips.

Consult a doctor if symptoms persist.
Skin contact: Remove contaminated clothing. Wash the skin with soap and water. 

Consult a doctor if the complaints persist.
Eye contact: Rinse with water (preferably use an eye bath) until the irritation disappears.
If symptoms persist, see a doctor.
Burns: Rinse with water until pain subsides. Remove clothing that has not burned into the skin 
Consult a doctor / hospital. If possible, continue flushing to a physician treatment.
General: When consulting a doctor, show the safety data sheet or label.

4.2. Most important symptoms and effects, both acute and delayed
The product releases organic solvent vapours which can cause lethargy and dizziness.

 In high concentrations, the vapours can cause headaches and intoxication. 

Prolonged or repeated skin exposure or inhalation vapours can damage the central nervous system. 
May cause slight irritation to skin and eyes. 

Can lead to hypersensitivity to skin contact. 

Symptoms include red irritation, swelling, blisters, and ulceration - which often occur develops slowly. 
Can be absorbed through the skin, with symptoms such as dizziness and headache.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms. No immediate special treatment required.

SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media: Extinguish with powder, foam or water mist. 

Use water or water spray for cooling stock that has not ignited.
Unsuitable extinguishing media: Do not use a water jet as it may spread the fire.
5.2. Special hazards arising from the substance or mixture
May generate harmful exhaust fumes containing carbon monoxide in case of fire.
5.3. Advice for firefighters
Only wear self-contained breathing apparatus with a chemical protective suit in places where (direct)
personal contact is likely. Remove containers from danger area if this can be done without risk.

Avoid it inhalation of vapours and flue gases - seek fresh air.

SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For persons other than the emergency services:
Stay upwind / keep away from the source. Stop leaks if this without risk is possible. 

Keep unnecessary personnel away.

-Wear safety glasses if at risk for splashes in the eyes. 
-Wear gloves. 
-Wear respiratory protection equipment.
Provide adequate ventilation. Smoking and open flames are prohibited.
For emergency responders: In addition to the above: Protective clothing equivalent to EN 368 type 3
are recommended.
6.2. Environmental precautions
Prevent leaking substance from entering the sewage system and / or surface water.
6.3. Methods and material for containment and cleaning up
Contain and absorb spillage with sand or other absorbent, non-combustible material and dispose of to suitable waste containers.
6.4. Reference to other sections
See section 8 for the type of protective equipment. See section 13 for disposal instructions.
SECTION 7: Handling and storage
7.1. Precautions for safe handling of the substance or mixture
Use the product in well-ventilated conditions. Running water and eyewash should be available
stand. 
Wash hands before breaks, before using the bathroom facilities and at the end of the working day.
Smoking and open flames are prohibited.

Take precautions against static discharge. 
Use non-sparking tools and explosion-proof equipment.

 7.2. Conditions for safe storage, including any incompatibilities Store safely, out of reach of children and not together with foodstuffs, animal feed, medicines, etc. 

Store it in the tightly closed original packaging.
 Do not expose to heat (eg sunlight).

 7.3. Specific end use

 No. 

SECTION 8: Exposure controls / personal protection

 8.1. Control parameters

 Occupational exposure


H = H (Skin absorption) - Substances that can pass through the skin relatively easily incorporated, which can make a substantial contribution to the total interior exposure, have an H-designation in the list. 

These substances must be taken in addition to measures adequate measures to prevent skin contact are also taken against inhalation.
TWA = Time Weighted Average
STEL 15 min = Time weighted mean

Measurement methods: 

Compliance with the occupational exposure limits can be checked through occupational hygiene measures.
Legal basis: Working Conditions Decree, Annex XIII, List of legal limit values.
8.2. Exposure controls
Appropriate technical measures:
Wear the personal protective equipment specified below.
Personal protective equipment, eye / face protection:
Wear safety goggles if there is a risk of splashing in the eyes. 

Eye protection should comply with EN 166.
Personal protective equipment, hand protection:
Wear gloves. Type of material: Nitrile rubber. There is no breakthrough time for this product determined. 
Change gloves regularly. 

Gloves must comply with AND 374.
The suitability and durability of gloves depends on the use.
 Eg. frequency and duration of contact, glove material thickness, functionality and chemical resistance. 

Always request information from the glove supplier.

Personal protective equipment, respiratory protection:
Light use (small amount, short exposure (less than 10 minutes)): 
Wear respiratory protection equipment.
 Filter type: A. Medium use (medium amount, medium exposure, 1-2 hours)): 

Wear respiratory protection with fresh air supply. 
Respiratory protection should meet one of the following standards: EN 136/140/145.

Control of environmental exposure:
Ensure compliance with local emissions regulations.

SECTION 9: Physical and chemical properties 

9.1. Information on basic physical and chemical properties

Parameter Value / unit Condition

 Liquid 

 Color : Different

 Odor : Characteristic 

Solubility : Insoluble in : Water 

Explosive properties : Non-explosive 

Oxidizing properties : No data Parameter Value / unit Comments

 pH (solution for use):  No data pH (concentrate) No data

--------------------------------------------------------------------------------------------------------------------------------------

Melting point: No data
Freezing point: No data
Initial boiling point and boiling range: 120.3 ° C
Flash point: 29 ° C DIN 53213
Evaporation rate: No data
Flammability (solid, gas): No data
Flammability limits: 315 ° C (DIN 51794)
Explosion limits: 0.6 - 8.0 vol%
Vapor pressure 6.7 - 8.2 hPa 20 ° C
Vapor density: No data
Relative density: No data
Partition coefficient n-octanol / water: No data
Auto-ignition temperature: Not self-igniting
Decomposition temperature: No data
Viscosity: No data
Odor Threshold: No data
9.2. Other information
Parameter Value / unit Comments
Density 0.996 g / cm3 (DIN 53217)
Kinematic viscosity 170-180 s (DIN 53211/4)
VOC 45.19%
Hard substance 54.8%

SECTION 10: Stability and reactivity
10.1. Reactivity
No known data.
10.2. Chemical stability
The product is stable when used according to the supplier's instructions.
10.3. Possibility of hazardous reactions
Product vapours are heavier than air and can spread over several floors. 
Vapours can form explosive mixtures on contact with air.
10.4. Conditions to avoid
Avoid heating and contact with ignition sources.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
May generate harmful exhaust fumes containing carbon monoxide in case of fire.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute oral toxicity:
Xylene, cas no 1330-20-7

Organism: Rat

Test Type:  LD50

Value: 5251 mg/kg


Swallowing can cause discomfort.

The product does not have to be classified. Based on existing data assumed that the classification standards have not been met.

Acute dermal toxicity:

 Xylene, cas no 1330-20-7


Organism: Rabbit

Test Type:  LD50

Value:  5000mg/kg

The product does not have to be classified. Based on existing data, it is assumed that the classification standards have not been met.

Acute Toxicity Inhalation:

Xylene, cas no 1330-20-7

Organism: Rat
Test Type: LD50 (Damp)
Exposure Time: 4H
Value: 29mg/l

The product does not have to be classified.
Based on existing data, it is assumed that the classification standards have not been met.

Skin corrosion / irritation: May cause mild irritation. The product does not have to be classified. 
No test data available.
Serious eye damage / eye irritation: Temporary irritation. The product does not have to be classified. 
No test data available.
Sensitisation of the respiratory tract or skin:
May cause hypersensitivity to skin contact. 
Symptoms are red irritation, swelling, blisters and ulceration - which often develops slowly.

Germ cell mutagenicity: The product does not have to be classified. 
No test data available.

Carcinogenic Properties: The product contains at least one substance suspected of being carcinogenic.
The product does not have to be classified. No test data available.

Reproductive toxicity: The product does not have to be classified. 
No test data available.

Single STOT exposure:

The product releases organic solvent vapors that can cause lethargy and dizziness cause.
In high concentrations, the vapours can cause headaches and intoxication cause. 
Can be absorbed through the skin, with symptoms such as dizziness and headache.

Repeated STOT exposure: 

Prolonged or repeated skin exposure or inhalation of vapours may occur central nervous system. 
The product does not have to be classified.
No test data available.

Aspiration hazard: 

The product does not have to be classified. 
No test data available.
Other toxicological effects: None

SECTION 12: Ecological information

12.1. Toxicity The product does not have to be classified. 
No test data available. 

12.2. Persistence and degradability
No test data available.
12.3. Bioaccumulation
No test data available.
12.4. Mobility in the soil
No test data available.
12.5. Results of PBT and vPvB assessment
No assessment has been carried out.
12.6. Other adverse effects
None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Avoid discharge into sewers or surface water.
 If this product becomes waste as supplied, it meets the criteria for hazardous waste.
 (European Directive 2008/98 /)

Collect spilt liquid and waste in sealed, leak-proof waste containers at the local hazardous waste landfill. 

Un-cleaned packaging must be disposed of via local waste collection.
Empty, cleaned packaging should be discarded for recycling.
Waste category: EWC code:

 Depends on industry and use, for example 08 01 11 * waste paint and varnish containing organic solvents or other dangerous substances
Wipers with organic solvents: 

EWC code: 15 02 02 Absorbents, filter material (including oil filters not otherwise specified), cleaning cloths and protective clothing contaminated with hazardous substances.

SECTION 14: Transport information
Land transport (ADR / RID)
14.1. UN number: 1263 14.4. 

Packing group: III
14.2. Proper Shipping Name in accordance with the model regulations of the UN:
PAINT 14.5. Environmental Hazards: 

The product should not if a hazard to the environment are labelled (symbol: fish and tree).
14.3.
Transport hazard class (es):
3
Hazard label (s): 3
Hazard identification number: 30 Tunnel restriction code: D / E
Other information: -
Inland waterway transport (ADN)
14.1. UN number: 1263 14.4.

Packing group: III
14.2. Proper Shipping Name according to the model regulations of the UN:
PAINT 14.5. Environmental Hazards: 

The product should not if a hazard to the environment are labelled (symbol:fish and tree).
14.3.
Transport hazard class (es):
3

Hazard label (s): 3
Transport in tanker vessels: - Other Information: -
Sea transport (IMDG)
14.1. UN number: 1263 14.4.

 Packing group: III
14.2. Proper Shipping Name according to the model regulations of the UN:
PAINT 14.5. Environmental Hazards: The product is not a 'marine pollutant '(MP).
14.3.
Transport hazard class (es):
3 Environmentally hazardous substance name (s):
Hazard label (s): 3
EmS: F-E, S-E IMDG Code segregation group:
- No -
Air transport (ICAO-TI / IATA-DGR)
14.1. UN number: 1263 14.4. Packing group: III
14.2. Proper Shipping Name according to the model regulations of the UN:
PAINT 14.5. Environmental Hazards: -
14.3.
Transport hazard class (es):
3
Hazard label (s): 3 Other Information: -
14.6. Special precautions for the user
No.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Does not apply.
SECTION 15: Regulatory information
15.1. Specific safety, health and environmental regulations / legislation for the substance or the
 
Mixture Special Provisions: 

Special caution is advised with regard to employees under the age of eighteen.

He/She must not perform any work involving harmful exposure to this product
Entails.
DIRECTIVE 2012/18 / EU (Seveso), P5c FLAMMABLE LIQUIDS: Column 2: 5000
t, Column 3: 50000 t.
Covered by:
Council Directive (EC) on the protection of young people at work.
15.2. Chemical safety assessment
Other Information: No Chemical Safety Assessment has been carried out.
SECTION 16: Other information
Version history and indication of changes:
2.0.0 11-12-2019 Bureau Veritas HSE - DOL 1-16 

1.0.0 15-12-2017 Bureau Veritas HSE / JOJ New SDS

Abbreviations:

PBT: Persistent, Bioaccumulative and Toxic 

STOT: Specific Target Organ Toxicity

 vPvB: Very Persistent and Very Bioaccumulative

Other Information: 

This safety data sheet has been prepared for and is applicable to this product
only. It is based on our current knowledge and the information that the supplier has about it
could provide the product at the time of preparation. 

The safety data sheet is in accordance with the law on drafting safety data sheets according to 1907/2006 / EC (REACH) and subsequent amendments.


Training advice:

 Thorough knowledge of this safety data sheet should be a priority.
Classification method: Calculation based on the hazards of the known components.
List of relevant H phrases
H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful by inhalation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Company: Bureau Veritas HSE Denmark A / S
Address: Oldenborggade 25-31
Postal code: 7000
Place: Fredericia
Country: DENMARK
Email: infohse@dk.bureauveritas.com
Telephone: +45 77 31 10 00
Homepage: http://www.hse.bureauveritas.dk